No, you can't have multiple Freeze Panes.
Two possible workarounds
Either copy the row you want to watch (totals ??) to the top row of th
screen above your header row, then with Freeze on below header, you would
have the totals visible at all times.
Or, Window>New Window then Window>Arrange Horizontal and set the 2nd
instance of the Worksheet with the rows to be watched visible just below the
working window.
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