Are you trying to:
A) Automatically insert a signature
From the main Microsoft Outlook window, on the Tools menu, click Options,
and then click the Mail Format tab.
In the Compose in this message format list, click the message format that
you want to use the signature with.
Under Signatures, select an e-mail account, and then choose the signatures
that you want to use for new messages and for replies and forwards. You can
use a different signature for each.
B) Manual insert of signature using word as default editor:
In the open message, click where you want to insert the signature in the
message body.
On the Insert menu, point to AutoText, point to Signature, and then click
the signature that you want to use.
Note:
When you use Word as your e-mail editor, the signature that you can manually
insert is AutoText that comes from the name and information that you typed
when you installed Microsoft Office. To view the information in Word, on the
Tools menu, click Options, and then click User Information.
When you use Word as your e-mail editor and you have Outlook automatically
apply your signature to messages that you send, forward, or reply to, the
signature comes from the e-mail signature that you created in one of the
following places:
In Word, on the Tools menu, click Options, click General, and then click
E-mail Options.
In Outlook, on the Tools menu, click Options, click Mail Format, and then
click Signatures.