SATA was specifically created for better speeds, and to eliminate the
need for master/slave settings.
To answer your question: You can't specify master/slave settings and
you can't have more than one SATA hard disk per channel. That's the way
they designed it. It's just physically impossible. MA/SL/CS jumpers are
a thing of the past.
Let me guess. You've run out of SATA channels and you want to add
another hard disk, right? Your solution to this would be to purchase a
PCI card that provides SATA connections, or to change your motherboard
to one that supports more SATA channels.
You could also just replace one of your hard disks with a larger one...
Most motherboards that are up to 2 years old or so should have at least
4 SATA channels on-board. My "ASUS A8N32-Sli-Deluxe" provides 6, with 16
more via the external eSATA connector.