http://www.globalwinusa.com/faqs/heatsink/color.html
Does heatsink color affect heat dissipation?
Black is the best thermal body in terms of being a absorber or
emitter. Let's assume a vacuum situation, if the surface "A" of a
black heatsink is totally covered at T1 (temperature 1) by another
black body at T2 (temperature 2), the black heatsink would get the
energy reflected from another black body at reflection energy
Ad(T14-T24) that we call "Stefan-Boltzmann" law of thermal radiation,
here refers to Stefan Boltzmann Constant, it is 5.6697 x 10-8 w/m2?K4.
Therefore if based on above, T1 is the temperature obtained from the
black heatsink onto CPU, T2 is the ambient temperature around CPU. So
if T14-T24 is a positive value, we know black is the best heat
dissipation transistor since there is no thermal source around CPU
inside PC case.