Sadly you can't. They only support play against random people across the
internet.
Don't quote me on this but I think there's a Hearts game on the MSN Zone
(http://zone.msn.com) which I believe you can invite in specific people to
play using something like Messenger.
Want to reply to this thread or ask your own question?
You'll need to choose a username for the site, which only take a couple of moments. After that, you can post your question and our members will help you out.