AFAIK this icon was never a standard part of any of the toolbars in any
version - however you can get to the feature under window / freeze pane menu
option or you can add the icon to your toolbars and use this.
To add the icon
- choose view / toolbars / customize from the menu
- choose the commands tab
- choose the windows and help category
- scroll down the right hand side until you see the icon for freeze panes
- click on it and drag it to one of your toolbars
- close the customize dialog box
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