It seems to me that if you copy your PST file to the thumb drive and then
change your profile on each machine to use that location as the default path
it should work fine (maybe slower than normal) assuming the drive is large
enough to handle it.
With Outlook closed, copy your PST to the jump drive and take it home with
you. Put it on the hard drive at home and open with that Outlook.
While you can actually make Outlook use the PST directly on the jump drive,
there are some side-effects that you could see if you use the exact same PST
with both PCs, shuttling it back and forth. You'd probably lose the use of
any rules it contains, for example.
If Exchange is not part of your mail profile, your rules will be in your PST
and they should be there if you configure your PST properly on the
destination PC. You may need to open each and reset the condition to get
them to work again, but they should be visible, at any rate.
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