No, because the PST is not attached to Outlook, it is referenced by the mail
profile Outlook is opening. Either the PST is in the profile or it is not.
You can certainly have two identical profiles, one with the PST reference and
one without, and at startup specify which profile Outlook should use.
You can also have two shortcuts that employ the /profile command switch, with
each shortcut specifying one of the profiles.
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