Regardless of what model of TV it is, PAL-M is the Australian standard. All
video cards sold here in Australia with Super Video Outputs on them will
generate the standard PAL-M S-Video analog signal. It is possible that your
video card might have the option in the driver to change the analog output
signal convention. In this case, set it to PAL. The video card driver manual
will indicate any such feature if it exists.
With regards to using such an analog display as the primary/only display, I
have had no luck at all getting it to work in the past. I was using a GeForce
2 card at the time and I would assume things have improved since then.
My only advice would be to try and configure the S-Video display as a
desktop extension with your current VGA. If that works, try assigning it as
your primary display. Once/If that works, remove the VGA/DVI display as part
of the dekstop extension.
In the past, I have been able to get the TV as a secondary display. In an
attempt to use it as the primary display, booting the computer wouldn't even
show the video card or mother board BIOS graphics on the TV.
I'm not saying it can't be done but I will guarentee you one thing. If you
get it to work, you will be one proud individual because it's an up-hill
battle all the way.