Excel will always open in a blank worksheet if you just select it from your
program list.
Get to your files by using File>Open while in Excel. You can also choose "My
Documents" and open specific Excel files from there. Alternatively, you can
create shortcuts on your desktop that will open a particular Excel document.
When you're in File>Open or "My Documents", you can right-click the file you
want to have a shortcut on your desktop and select "Send To> Desktop (create
shortcut)." So now, when you click that icon on your desktop, it will open
Excel and that particular document.
If they are all kept in the same directory, Jim Cone's nifty free Add-in
called "ListFiles" will do a bang-up job of not only listing them, but
creating a link to each.
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