If you are so pedantic that you must have your key fields in
sequenctial order, this can be acheived by opening the table in design
view, deleting the field, then switching to table view so that you can
see the data. Copy all of this data, then delete it all. Save the
table. Open the table in design view add an autonumber field, save,
and paste the data. Needless to say that you will have to delete any
relationships before you delete the primary key. Furthermore you will
be unable to re-establish the links in any meaningful way as the data
will have changed irrevocably. But if your database only consists of
one table, or the tables within it in no way relate to another tables,
Go for your Life!
Good luck,