Conveniently ? perhaps with Device Manager, Disk Drives. Examine
the Vendor/Model descriptor, such as ST33206... Then look up the
specifications on the vendor's web site. Physically opening the case &
checking cables is another option but isn't always practical if the PC
is hard to access. You can also use a Hardware/Software inventory
tool like Belarc Advisor to get technical information.
http://www.belarc.com/free_download.html
*You have to be careful, some SATA controllers are categorized in
XP as SCSI but aren't since SCSI is a parallel technology and SATA
is Serial format.