You could create a small .vbs (scripting file) and run that.
The script opens excel, opens your file, prints the workbook, closes your file
and closes excel.
Copy this into notepad and save that file as: something.vbs
Dim XL
Dim XLWkbk
Set XL = CreateObject("excel.application")
XL.Visible = True
Set XLWkbk = XL.Workbooks.Open("C:\my documents\excel\book11.xls")
XLWkbk.PrintOut
XLWkbk.Close False
XL.Quit
Set XLWkbk = Nothing
Set XL = Nothing
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Adjust the name/location of the file to print.