There are programs that can recover product keys from the windows registry.
However, if you did a clean re-install of XP, as opposed to a repair
install, the old registry would have been destroyed. Still, you might want
to try this small program:
Alternatively, think about not re-installing Microsoft Works and instead
installing Open Office. Open Office is much like the full Microsoft Office,
but it is free. It can read/write DOC, XLS, and many other common formats.
See following link:
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