Outlook Express uses Identites, not Outlook. If you are using Outlook Express and would like to password the Identity, follow the steps below;
1. Open Outlook Express
2. Click on File > Identities > Manage identity
3. Select the Identity you want to password
4. Click Properties
5. Check the box "Require a password"
If you are using Outlook, you will need to password protect the .PST file itself.
Regards,
Scott Atkins MCSE, MCSA
Partner Technical Lead - Outlook
Microsoft Technical Support
for Platforms and Business Applications
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