It's not clear what you hope to accomplish here, but here are some thoughts
about what the subject.
First, you create and format forms in the Access application itself. That's
one of the basic development tools provided in Access. However, you start by
defining and creating the tables to store the data and then you can design
and create the forms to present it.
Then, your users must have a copy of either the full Access application, or
the Access run-time, to open and use your database. If they have an Access
license, all they need to do is start the Access program and open your accdb
with it. If not, you can make the run-time available and create a desktop
shortcut for your accdb which invokes the run-time program to open and run
the accdb.
There is no provision for creating exe files form accdb files. Other formats
(accdr or accde) can be created for specific purposes.
Please post back with more details on your goals, so we can offere more
focussed feeback to you.