Not if you use the Envelopes and Labels dialog. If you use an envelope
template, you can include a macro that prints to a specific printer. If the
envelope is attached to the document, however, there is no way (at least
none that I know of) to print the envelope and document to different
printers (you can assign different trays of the same printer).
--
Suzanne S. Barnhill
Microsoft MVP (Word)
Words into Type
Fairhope, Alabama USA
http://word.mvps.org