Print screen inserts the screen image into the clipboard. As far as using
it to print, some applications will let you customize how the application
reacts on a key press, so it's up to the application. Or you can develop
your own keyboard drivers.
Google for Printkey 2000 version 5.10. It's free and works on Win2K. Not
spyware or adware.
After installation the program opens when you select the Print Screen
key. Allows you to select all or part of the screen. Offers a variety of
printing options.