The ATX and EPS standards are described here:
ATX
http://www.formfactors.org
EPS
http://ssiforum.org
(EPS is mostly used with multi-cpu pc servers though.)
I'd expect most of todays generic desktops to use ATX12V v2.x type PSU:s
but some PC brands may want to roll their own for mechanics and connectors.
The older ATX12V v1.3 was mainly a +5V supply, but ATX12V v2.x has more
+12V power, so it depends if you replace in an older PC or a newer.
Some PSU:s include adaptors for older connectors (AT type), but the load
balancing may still be wrong for the system.
If one upgrades a box from an old pentium mobo to a P4, and/or changes
to a powerhungry graphics card, while keping an older PSU, it's possible
it gets overloaded & breaks, and they'd need a later ATX version
replacement. (Homebuilders would probably know enough to get their own
PSU, not needing repairmen though.)
So do you expect to replace PSU:s on *new* PC:s or on old PC:s?
Which ones break more often? I'd guess it's both ends of the spectrum,
only the older PC:s get replaced, not repaired?
/Rolf