From XP HELP:
To set personal printing preferences
[[Open Printers and Faxes.
Right-click the icon for the printer you are using, and then click Printing
Preferences.
Click the Layout and Paper/Quality tabs and the Advanced button to see the
available choices, and make changes as needed.
Notes
To open Printers and Faxes, click Start, point to Settings, click Control
Panel, and then double-click Printers and Faxes.
When you set personal printing preferences using Printers and Faxes, the
default settings are changed for all documents you print to that printer.
These preferences include the page orientation, the tray from which paper is
sent, and the number of copies printed. Making these changes requires that
you have the Print permission, which is one of several printer permissions.
You can change printing preferences for individual documents from within a
software program. To do so, click Page Setup (or Print Setup) on the
program's File menu, and then make selections. To set the printing default
for all users connected to the printer, see Set printing defaults.
You can also open printing preferences in Printers and Faxes by clicking a
printer, and then clicking Select printing preferences under Tasks on the
left side of the window. This option is available only if folders are set to
look like a Web page and a printer is selected.]]