You can always add files to a CD-R, until the disk is full, or you choose to
close the disk. When you add more files, a new session is created and files
can be added to those already on the disk. You cannot recover any space used
by previous sessions, but you may (software depending) be able to delete
(hide) files already written.
With a CD-RW, you can do exactly the same as with a CD-R, only when the disk
becomes full, or no longer any use, you can erase it and start again. As
with a CD-R, you cannot recover space from previous sessions, you can only
add to the disk, but you have the option of blanking it and starting again.