You can create a new table with an AutoNumber field, and import all the
existing records.
1. On the Tables tab of the Database window, select your table.
Copy (Ctrl+C.)
Paste (Ctrl+V.)
Tell Access you want Structure only, and supply the new name.
2. Open this new table in design view.
Delete the Number field.
Add an AutoNumber field instead.
Make the AutoNumber as primary key.
Save.
Close.
3. Create a new query, using the original table.
Change it to an Append query (Append on query menu.)
Answer that you want the records appended to the new table.
Drag all fields into the grid.
Check they are all assigned to the right fields (including the AutoNumber.)
Run the query.
4. After checking the results, delete any relations your old table has
(Relationships on Tools menu).
Then delete the table.
Compact: Tools | Database Utilities | Compact.
Rename the new table with the old name if desired.
Recreate the relationships.
Before you reuse the same name for the table, make sure the Name AutoCorrect
boxes are unchecked under:
Tools | Options | General
Explanation of why:
http://allenbrowne.com/bug-03.html